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Introduction
Lithium Niobate (LiNbO3 or LN) is widely used as frequency doublers for wavelength>1µm, optical parametric oscillators (OPOs) pumped at 1064 nm as well as quasi-phase-matched (QPM) devices. Additionally due to its large Electro-Optic (E-O) and Acousto-Optic (A-O) coefficients, LiNbO3 crystal is the most commonly used material for Pockel cells, Q-switches and phase modulators, waveguide substrates, and surface acoustic wave (SAW) wafers, etc. CASTECH can provide LiNO3 crystals with high quality and large size for all these applications.
CASTECH provides
Basic Properties
Table 1. Chemical and Physical Properties
|
Crystal Structure |
Trigonal, Space group R3c, Point group 3m |
|
Lattice Parameter |
a = 5.148 Å, c = 13.863 Å |
|
Melting Point |
1253℃ |
|
Curie Temperature |
1140℃ |
|
Mohs Hardness |
5 Mohs |
|
Density |
4.64 g/cm3 |
|
Elastic Stiffness Coefficients |
CE11 = 2.33 ( × 1011 N/m2) CE33 = 2.77 ( × 1011 N/m2) |
Table 2. Optical and Nonlinear Optical Properties
|
Transparency Range |
420-5200 nm |
|
Optical Homogeneity |
~5 ×10-5 /cm |
|
Refractive Indices |
ne = 2.146, no = 2.220 @1300 nm ne = 2.156, no = 2.232 @1064 nm ne = 2.203, no = 2.286 @632.8 nm |
|
NLO Coefficients |
d33 = 86 × d36 (KDP) d31 = 11.6 × d36 (KDP) d22 = 5.6 × d36 (KDP) |
|
Effective NLO Coefficients |
deff (I) = d31 sinθ - d22 cosθ sin3Φ deff (II) = d22 cos2θ cos3Φ |
|
Sellmeier Equations (λ in μm) |
no2 = 4.9048 + 0.11768 / (λ2 - 0.04750) - 0.027169 λ2 ne2 = 4.5820 + 0.099169 /(λ2 - 0.04443) - 0.02195 λ2 |
|
Damage Threshold |
100 MW/cm2 (10 ns, 1064 nm) |
Table 3. Thermal and Electrical Properties of LiNbO3
|
Thermal Conductivity |
38 W/m/K @25 ℃ |
|
Thermal Expansion Coefficients (at 25℃) |
//a, 2.0 × 10-6 /K //c, 2.2 × 10-6 /K |
|
Resistivity |
2×10-6 Ω·cm @200 ℃ |
|
Dielectric Constants |
εS11/ε0 = 43, εT11/ε0 = 78 εS33/ε0 = 28, εT33/ε0 = 32 |
|
Piezoelectric Strain Constant |
D22 = 2.04 × 10-11 C/N D33 = 19.22 × 10-11 C/N |
|
Electro-Optic Coefficients |
γT33 = 32 pm/V, γS33 = 31 pm/V, γT31 = 10 pm/V, γS31 = 8.6 pm/V, γT22 = 6.8 pm/V, γS22 = 3.4 pm/V |
|
Half-Wave Voltage, DC Electrical field // z, light ⊥ z; Electrical field // x or y, light // z; |
3.03 KV 4.02 KV |
Table 4. Specifications
|
Dimension Tolerance |
(W ± 0.1 mm) × (H ± 0.1mm) × (L ± 0.2mm) |
|
Clear Aperture |
Central 90% of the diameter |
|
Surface Quality (Scratch/Dig) |
20/10 to MIL-PRF-13830B |
|
Flatness |
λ/8 @633 nm |
|
Transmitted Wavefront Distortion |
≦ λ/4 @633 nm |
|
Parallelism |
20 arc sec |
|
Perpendicularity |
≦ 15 arc min |
|
Angle Tolerance |
≦ ±0.5° |
|
Quality Warranty Period |
One year under proper use |
AR-coatings
CASTECH provides the following AR-coatings: